
Substrates, particularly thermoplastic resins and polymers, are plated with metals by pre-treatment of the substrate with phosphorus in an organic solvent to deposit phosphorus at the surface, followed by contacting the treated surface wit a metal salt or complex thereof, to form a metal-phosphorus compound. Thereafter the substrate is subjected to an aqueous hypophosphite solution. The resulting treated surface is conductive and can be readily electroplated by conventional techniques.











