Ammonium sulfate nitrate composite materials useful as fertilizers having desirable levels of nitrate ions, superior stability against detonation, higher density, greater resistance to moisture, and a method for their manufacture. The ammonium sulfate nitrate composites have as essential constituents ammonium sulfate and the NH.sub.4 SO.sub.4.2(NH.sub.4 NO.sub.3) double salt with less than 5 wt. % in combined total of the more hazardous NH.sub.4 SO.sub.4.3(NH.sub.4 NO.sub.3) double salt and ammo...