
It has been known that metals of groups IV-B, V-B, and VI-B of the periodic table, namely chromium, hafnium, molybdenum, niobium, tantalum, titanium, tungsten, vanadium, and zirconium and alloys thereof can be electrodeposited as dense, structurally coherent plates from a solution of the refractory metal flouride in a molten alkali-fluoride mixture in which the concentration of oxygen is reduced to and maintained at a sufficiently low level. It is shown that niobium may be plated at a lower temp...











