A method for removing sodium oxalate from a caustic aluminate liquor produced using the Bayer process is disclosed which includes the steps of initially washing all the product aluminum trihydroxide obtained from the precipitation circuit to remove any crystalline sodium oxalate, thereby preventing any further sodium oxalate precipitation within the aluminum trihydroxide precipitators. This causes the dissolved sodium oxalate concentration to rise to a level which is conducive to economic remova...

The invention relates to dicopper(I) oxalate complexes stabilized by neutral Lewis bases, such as alkenes or alkynes, and to the use of dicopper(I) oxalate complexes as precursors for the deposition of metallic copper, in which the neutral Lewis bases used are alkynes, alkenes, triarylphosphines, CO or isonitriles.

A process for the preparation of oxalate esters by the catalytic oxidative carbonylation of carboxylic ortho esters with carbon monoxide and oxygen-containing gas in the presence of a metal salt catalyst, an amine base and a catalytic amount of an alcohol. Preferably a catalytic amount of particular metal oxidizing salts is employed along with a catalytic amount of an acid or an amine salt compound. Alternatively various counterions and ligands of the metal salt catalysts may be employed.

The subject invention pertains to polynucleotides encoding the enzyme oxalate decarboxylase from the filamentous fungus Aspergillus niger and methods of use. The subject invention also pertains to methods of using the enzyme oxalate decarboxylase from Bacillus subtilis.

There is disclosed an improved process for preparing a superconducting composition having the formula MBa.sub.2 Cu.sub.3 O.sub.x wherein M is selected from the group consisting of Y, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, Yb and Lu; x is from about 6.5 to about 7.0; said composition having a superconducting transition temperature of about 90 K; said process consisting essentially of heating a precursor powder in an oxygen-containing atmosphere at a temperature from about 875.degree. C. to about 950.deg...

This invention is directed to the use of an improved composition for inhibiting the precipitation of calcium oxalate in aqueous systems. The composition contains: (a) a water soluble phosphate; and (b) a water soluble polycarboxylate having a weight average molecular weight of about 7,000 to about 9,000; wherein the ratio of component (a) to component (b) ranges from 10:1 to 1:10.

A method for providing a hydrogen peroxide reactive chemiluminescent system hich operates efficiently as one unit. The method avoids the necessity for separately storing two reactive components. It comprises adding under oxygen free conditions an organic compound selected from the group consisting of anthrahydroquinone, 2-ethylanthrahydroquinone, 2-tertiarybutylanthrahydroquinone, and benzoin to a solution of an oxalate ester, a fluorescer, and a catalyst, if one is required. Upon exposure of th...

In a method of processing contaminated sodium oxalate which becomes available in a separating stage succeeding the digestion of bauxite in accordance with the Bayer process, chemicals used in the digesting process are recovered in that moist sodium oxalate which has been separated is dried with the hot exhaust gases from a rotary kiln jointly with aluminum hydroxide or aluminum oxide hydrate and/or reactive alumina at a mole ratio of aluminum to sodium of at least 0.8 and the dried product is de...

In a method for processing contaminated sodium oxalate which becomes available in a separating stage succeeding the digestion of bauxite in accordance with the Bayer process, chemicals used in the digesting process are recovered in that the moist sodium oxalate which has been separated is dried with the hot exhaust gases from a fluidized bed, particularly a circulating fluidized bed, jointly with aluminum hydroxide or aluminum oxide hydrate and/or reactive alumina at a mole ratio of aluminum to ...

The method is carried out in the following manner: An aqueous mixture solution containing barium chloride and titanium chloride is added into an aqueous oxalic acid solution, so that barium titanyl oxalate would be precipitated. Then the precipitates are aged, washed and filtered. The filtered barium titanyl oxalate precipitates are crushed, and dried. Then a thermal decomposition is carried out to obtain a agglomerated barium titanate powder, and this is crushed again to obtain the final barium...