
A process for the preparation of liquid ketones which comprises coupling a saturated aldehyde, e.g., acetaldehyde, with an alpha-olefin, e.g., ethylene, in the presence of an organic hydroperoxide initiator and a metal-containing compound as the catalyst therefor, e.g., cobalt(II) acetylacetonate. The novel process results in good productivities and high initiator efficiencies.











