
Polydiorganosiloxanes of the general formula R.sup.1--(OSiR.sub.2).sub.nOH (I) are prepared by reacting hexaorganocyclotrisiloxanes of the formula (R.sub.2SiO).sub.3 (II) with alcohols of the formula R.sup.1--OH (III) where each R is the same or different and is a monovalent, optionally substituted hydrocarbon radical, R.sup.1 is a monovalent, optionally substituted hydrocarbon radical and n is an integer of at least 3, in the presence of a carbonate salt as a catalyst.











