A high yield (92-95 percent) catalytic process for the production of muconodinitrile (1,4-dicyano-1,3-butadiene) by oxidative vapor phase dehydrogenation of 1,4-dicyanobutenes has been developed. The process is applicable to each of the following starting materials: (a) 1,4-dicyano-1-butene, (b) 1,4-dicyano-2-butene, and (c) a mixture of the last two isomers. The preferred catalysts used are supported bismuth phosphomolybdate or bismuth molybdate systems and the range of operating temperature is...