A photopolymerizable composition comprising: I. an unsaturated polyester having an average molecular weight of about 1,500 to 50,000, containing in the molecule at least one weight percent of a segment, measured from one ester bond to the next ester bond, having a molecular weight of about 80 to 5,000, and containing about 2 .times. 10.sup.-.sup.3 to 2 .times. 10.sup.-.sup.4 mole of ethylenic unsaturation per gram of unsaturated polyester; Ii. about 10 to 80 weight percent of at least one ethyle...